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What are fuel cells?

A fuel cell is an electrochemical device that extracts electricity directly from a fuel (typically hydrogen). A single cell consists of an electrolyte sandwiched between an anode and a cathode. Hydrogen is supplied to the anode and a catalyst separates the gas into negatively charged electrons (e-) and positively charged ions (H+). The electrons (e-) flow through an external load to the cathode. The hydrogen ions (H+) migrate through the electrolyte to the cathode where they combine with oxygen and the electrons (e-) to produce water. Each cell only produces a small voltage (typically 0.7V) and so many of these are stacked together to give the required level of power.

In contrast to a normal battery, a fuel cell does not become “flat” since new fuel is continuously supplied to the cell. It can therefore supply constant power like an engine or a turbine although it does not have any moving parts.

Fuel cells are inherently clean as the only emissions are electricity, water and heat (when fueled with pure hydrogen). They also offer significant improvements in efficiency over other energy generation technologies and with minimal noise (the cell is silent but peripheral equipment for pumping fuel etc produce some sound).

There are different types of fuel cells as shown in the table below. Currently the most popular ones are the PEM (for portable, automotive and stand-by power applications) and SOFC (for larger stationary power generation requirements).
For more information see: www.etscience.co.za

Types of fuel cells

Type
Electrolyte
Fuel/oxidant
Operating temperature (°C)
Efficiency (%)
Potential applications
Alkaline (AFC)
Potassium or sodium hydroxide
H2/O2 (CO2 removed by scrubber)
50-200
40-60
Up to 100 kW – space, transport, military
Proton exchange membrane (PEM)
Sulphonic acid in solid polymer membrane
H2 and O2 from air
50-125
35-45
Up to 500 kW – commercial and residential distributed power, transport
Direct methanol (DMFC)
Sulphonic acid in solid polymer membrane or sulphuric acid solution Methanol and O2 from air
50-110
40-50
Up to 10 kW – small, portable power, military, transport
Phosphoric acid (PAFC)
Phosphoric acid H2 and O2 from air
170-210
40-50
Up to 10 MW – power generation, cogeneration (up to 80% efficient), buses
Molten carbonate (MCFC)
Molten lithium, sodium or potassium carbonate H2 from hydrocarbon fuel internal reforming and O2 from air
600-700
50-60
Up to 100 MW – power generation, cogeneration (up to 80% efficient)
Solid oxide (SOFC)
Solid ceramic – zirconium oxide H2 from hydrocarbon fuel internal reforming and O2 from air
650-1000
45-55
Up to 100 MW – power generation, cogeneration (up to 80% efficient), small APU’s for transport
 
 
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